Evolution of PAHs in photodissociation regions: Hydrogenation and charge states

Various studies have emphasized variations of the charge state and composition of the interstellar polycyclic aromatic hydrocarbon (PAH) population in photodissociation regions (PDRs). We aim to model the spatial evolution of the charge and hydrogenation states of PAHs in PDRs. We focus on the specific case of the north-west (NW) PDR of NGC 7023 and also discuss the case of the diffuse interstellar medium (ISM). The physical conditions in NGC 7023 NW are modelled using a state-of-the-art PDR code. We then use a new PAH chemical evolution model that includes recent experimental data on PAHs and describes multiphoton events. We consider a family of compact PAHs bearing up to 96 carbon atoms. The calculated ionization ratio is in good agreement with observations in NGC 7023 NW. Within the PDR, PAHs evolve into three major populations: medium-sized PAHs (50<Nc<90) are normally hydrogenated, larger PAHs (Nc>90) can be superhydrogenated, and smaller species (Nc<50) are fully dehydrogenated. In the cavity, where the fullerene C60 was recently detected, all the studied PAHs are found to be quickly fully dehydrogenated. PAH chemical evolution exhibits a complex non-linear behaviour as a function of the UV radiation field because of multiphoton events. Steady state for hydrogenation is reached on timescales ranging from less than a year for small PAHs, up to 10000 years for large PAHs at Av=1. We identified critical reactions that need more studies. Our new model allows us to rationalize the observational constraints without any fitting parameter. PAHs smaller than 50 carbon atoms are not expected to survive in the NGC 7023 NW PDR. A similar conclusion is obtained for the diffuse ISM. Carbon clusters turn out to be end products of PAH photodissociation, and the evolution of these clusters needs to be investigated further to evaluate their impact on the chemical and physical evolution of PDRs.Comment: 16 pages, 10 figures; Accepted for publication in A&

"Whose data is it anyway?" The implications of putting small area-level health and social data online

International audienceThe planetary exospheres are poorly known in their outer parts, since the neutral densities are low compared with the instruments detection capabilities. The exospheric models are thus often the main source of information at such high altitudes. We present a new way to take into account analytically the additional effect of the radiation pressure on planetary exospheres. In a series of papers, we present with an Hamiltonian approach the effect of the radiation pressure on dynamical trajectories, density profiles and escaping thermal flux. Our work is a generalization of the study by Bishop and Chamberlain (1989). In this second part of our work, we present here the density profiles of atomic Hydrogen in planetary exospheres subject to the radiation pressure. We first provide the altitude profiles of ballistic particles (the dominant exospheric population in most cases), which exhibit strong asymmetries that explain the known geotail phenomenon at Earth. The radiation pressure strongly enhances the densities compared with the pure gravity case (i.e. the Chamberlain profiles), in particular at noon and midnight. We finally show the existence of an exopause that appears naturally as the external limit for bounded particles, above which all particles are escaping

Projet de paysage participatif à Villandry

Cette recherche s’inscrit dans le cadre du projet intitulé « Participation des populations et renouvellement des pratiques paysagistes. Une approche par l’expérimentation et la comparaison des méthodes » au sein du programme « Paysage et Développement durable II », porté par le MEDDE. L’originalité de ce projet tient en partie à la collaboration entre des enseignants-chercheurs de trois écoles de paysage françaises (Angers, Versailles et Bordeaux) et des paysagistes, engagés ensemble dans deux démarches expérimentales. Nous revenons plus particulièrement dans cet article sur l’une des deux expérimentations, conduite sur la commune de Villandry dans le Val de Loire

Diagnostics for specific PAHs in the far-IR: searching neutral naphthalene and anthracene in the Red Rectangle

Context. In the framework of the interstellar polycyclic aromatic hydrocarbons (PAHs) hypothesis, far-IR skeletal bands are expected to be a fingerprint of single species in this class. Aims. We address the question of detectability of low energy PAH vibrational bands, with respect to spectral contrast and intensity ratio with ``classical'' Aromatic Infrared Bands (AIBs). Methods. We extend our extablished Monte-Carlo model of the photophysics of specific PAHs in astronomical environments, to include rotational and anharmonic band structure. The required molecular parameters were calculated in the framework of the Density Functional Theory. Results. We calculate the detailed spectral profiles of three low-energy vibrational bands of neutral naphthalene, and four low-energy vibrational bands of neutral anthracene. They are used to establish detectability constraints based on intensity ratios with ``classical'' AIBs. A general procedure is suggested to select promising diagnostics, and tested on available Infrared Space Observatory data for the Red Rectangle nebula. Conclusions. The search for single, specific PAHs in the far-IR is a challenging, but promising task, especially in view of the forthcoming launch of the Herschel Space Observatory.Comment: 13 pages, 13 figures, accepted for publication in A&

La convention européenne au prisme d’une recherche-action de médiation paysagère en Val de Loire (Villandry)

Cette communication se propose de questionner deux apports majeurs de la Convention européenne du paysage. Le premier est l’articulation qu’elle construit entre paysage et démocratie : initié par le Conseil de l’Europe dont la mission est de promouvoir les valeurs démocratiques, cette convention associe les enjeux de paysage aux enjeux de la démocratie locale. Elle fait la promotion des démarches participatives pour conduire l’action publique paysagère, sans toutefois donner un contenu précis à cette participation par et pour le paysage. Cette absence de définition est d’autant plus remarquable que l’autre apport majeur de ce texte réside dans les définitions terminologiques qu’il propose sur plusieurs notions-clé de l’action publique paysagère : paysage, objectifs de qualité paysagère, politiques publiques du paysage (protection, gestion, aménagement des paysages). Notre communication cherchera à illustrer et questionner ces deux dimensions de la convention européenne du paysage à partir d’une démarche de médiation paysagère actuellement mise en œuvre par des chercheurs et/ou paysagistes dans le cadre d’un programme de recherche (volet « paysage et participation » du programme « Paysage et développement durable », financé par le Ministère de l’écologie – France) sur une petite commune du Val de Loire (avec le soutien de la mission Loire UNESCO). Dans un premier temps elle permettra de décrire un processus en cours de projet de paysage participatif (2012/2014) en s’arrêtant sur les objectifs, les phases, les outils, les limites de cette démarche. Dans un deuxième temps, la communication éclairera avec un point de vue critique chacune des définitions des termes de la CEP au regard des premiers résultats issus de la recherche-action (enquêtes individuelles auprès des habitants, puis ateliers collectifs)

Formation and destruction of polycyclic aromatic hydrocarbon clusters in the interstellar medium

The competition between the formation and destruction of coronene clusters under interstellar conditions is investigated theoretically. The unimolecular nucleation of neutral clusters is simulated with an atomic model combining an explicit classical force field and a quantum tight-binding approach. Evaporation rates are calculated in the framework of the phase space theory and are inserted in an infrared emission model and compared with the growth rate constants. It is found that, in interstellar conditions, most collisions lead to cluster growth. The time evolution of small clusters (containing up to 312 carbon atoms) was specifically investigated under the physical conditions of the northern photodissociation region of NGC 7023. These clusters are found to be thermally photoevaporated much faster than they are reformed, thus providing an interpretation for the lowest limit of the interstellar cluster size distribution inferred from observations. The effects of ionizing the clusters and density heterogeneities are also considered. Based on our results, the possibility that PAH clusters could be formed in PDRs is critically discussed.Comment: 14 pages, 14 figures. Astronomy & Astrophysics, accepted for publicatio

Projet de paysage participatif à Villandry : retours d’expérience d’une recherche-action

Cette recherche s’inscrit dans le cadre du projet intitulé « Participation des populations et renouvellement des pratiques paysagistes. Une approche par l’expérimentation et la comparaison des méthodes » au sein du programme « Paysage et Développement durable II », porté par le MEDDE. L’originalité de ce projet tient en partie à la collaboration entre des enseignants-chercheurs de trois écoles de paysage françaises (Angers, Versailles et Bordeaux) et des paysagistes, engagés ensemble dans deux démarches expérimentales. Nous revenons plus particulièrement dans cet article sur l’une des deux expérimentations, conduite sur la commune de Villandry dans le Val de Loire

Estimated IR and phosphorescence emission fluxes for specific Polycyclic Aromatic Hydrocarbons in the Red Rectangle

Following the tentative identification of the blue luminescence in the Red Rectangle by Vijh et al. (2005), we compute absolute fluxes for the vibrational IR emission and phosphorescence bands of three small polycyclic aromatic hydrocarbons. The calculated IR spectra are compared with available ISO observations. A subset of the emission bands are predicted to be observable using presently available facilities, and can be used for an immediate, independent, discriminating test on their alleged presence in this well-known astronomical object.Comment: accepted for publication on A&

Visible photodissociation spectroscopy of PAH cations and derivatives in the PIRENEA experiment

The electronic spectra of gas-phase cationic polycyclic aromatic hydrocarbons (PAHs), trapped in the Fourier Transform Ion Cyclotron Resonance cell of the PIRENEA experiment, have been measured by multiphoton dissociation spectroscopy in the 430-480 nm spectral range using the radiation of a mid-band optical parametric oscillator laser. We present here the spectra recorded for different species of increasing size, namely the pyrene cation (C16H10+), the 1-methylpyrene cation (CH3-C16H9+), the coronene cation (C24H12+), and its dehydrogenated derivative C24H10+. The experimental results are interpreted with the help of time-dependent density functional theory calculations and analysed using spectral information on the same species obtained from matrix isolation spectroscopy data. A kinetic Monte Carlo code has also been used, in the case of pyrene and coronene cations, to estimate the absorption cross-sections of the measured electronic transitions. Gas-phase spectra of highly reactive species such as dehydrogenated PAH cations are reported for the first time

A general model for the identification of specific PAHs in the far-IR

Context. In the framework of the interstellar PAH hypothesis, far-IR skeletal bands are expected to be a fingerprint of single species in this class. Aims. A detailed model of the photophysics of interstellar PAHs is required for such single-molecule identification of their far-IR features in the presently available Infrared Space Observatory data and in those of the forthcoming Herschel Space Observatory mission. Methods. We modelled the detailed photophysics of a vast sample of species in different radiation fields, using a compendium of Monte-Carlo techniques and quantum-chemical calculations. This enabled us to validate the use of purely theoretical data and assess the expected accuracy and reliability of the resulting synthetic far-IR emission spectra. Results. We produce positions and intensities of the expected far-IR features which ought to be emitted by each species in the sample in the considered radiation fields. A composite emission spectrum for our sample is computed for one of the most favourable sources for detection, namely the Red Rectangle nebula. The resulting spectrum is compared with the estimated dust emission in the same source, to assess the dependence of detectability on key molecular parameters. Conclusions. Identifying specific PAHs from their far-IR features is going to be a difficult feat in general, still it may well be possible under favourable conditions.Comment: 14 pages, 9 figures + 18 pages of online appendix. Accepted for publication in A&A (09/06/2006